6533b7d3fe1ef96bd126013f
RESEARCH PRODUCT
[(1R,4S)-(+)-3-Benzoyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-olato-κ2 O 2,O 3](η4-norbornadiene)rhodium(I)
Mustapha Ait AliMohamed Anoir HarradCorrado RizzoliBrahim BoualyLarbi El Firdoussisubject
Metal-Organic PapersBicyclic moleculeChemistryNorbornadienechemistry.chemical_elementGeneral ChemistryDihedral angleCondensed Matter PhysicsRing (chemistry)BioinformaticsMedicinal chemistryRhodiumMetalchemistry.chemical_compoundvisual_artvisual_art.visual_art_mediumGeneral Materials ScienceChelationCoordination geometrydescription
In the title complex mol-ecule, [Rh(C(17)H(19)O(2))(C(7)H(8))], the rhodium(I) metal centre is coordinated by the O atoms of a benzoyl-camphorate anion and the C=C bonds of the norbornadiene mol-ecule into a slightly distorted square-planar coordination geometry. The six-membered chelate ring is essentially planar (r.m.s. deviation = 0.0378 Å) and forms a dihedral angle of 31.67 (11)° with the phenyl ring.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2010-07-10 | Acta Crystallographica Section E: Structure Reports Online |