Synthesis and X-ray Crystallographic Characterization of (μ-(Diphenylphosphino)phenyl-C2,P)palladium Bromide. A Novel Tetranuclear Metalated Compound

6533b7d3fe1ef96bd12612e7

RESEARCH PRODUCT

Synthesis and X-ray Crystallographic Characterization of (μ-(Diphenylphosphino)phenyl-C2,P)palladium Bromide. A Novel Tetranuclear Metalated Compound

† Mercedes Sanaú M. Angeles Ubeda Pascual Lahuerta Atta M. Aarif Abel García-bernabé Francisco Estevan

subject

Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Bromide Cluster (physics)X-ray chemistry.chemical_element Crystal structure Physical and Theoretical Chemistry Cleavage (embryo)Cis–trans isomerism Palladium

description

The synthesis and crystal structure of a tetranuclear palladium cluster, [Pd(PC)Br]4 (PC) = [P(C6H4)Ph2]-), is described. Cleavage of this cluster with phosphines yields the mononuclear species Pd(PC)Br(P) in the form of cis and trans isomers. An equilibrium between mono- and tetranuclear species is observed for P = PCBr.

year	journal	country	edition	language
1997-12-01	Inorganic Chemistry

https://doi.org/10.1021/ic9702734

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