6533b7d4fe1ef96bd1261d6e

RESEARCH PRODUCT

Synthesis and Characterization of Yttrium Complexes Containing a Tridentate Linked Amido−Cyclopentadienyl Ligand

Thomas P. SpaniolJun OkudaKai C. Hultzsch

subject

Inorganic ChemistryDilithiumchemistry.chemical_compoundCyclopentadienyl complexStereochemistryChemistryLigandOrganic Chemistrychemistry.chemical_elementYttriumPhysical and Theoretical ChemistryMedicinal chemistry

description

The reaction of dilithium salts of the tridentate linked amido−cyclopentadienyl ligands Li2(C5Me4SiMe2NCH2CH2X) (X = OMe, NMe2, CH2OMe) with [Y(o-C6H4CH2NMe2)Cl2(LiCl)(THF)4] and Y(η5-C5H5)Cl2(THF)3 give chloro-bridged ate complexes of the type [Li(THF)][Y(η5:η1-C5Me4SiMe2NCH2CH2X)(R)Cl], where R = o-C6H4CH2NMe2, η5-C5H5.

https://doi.org/10.1021/om970701d