6533b7d4fe1ef96bd1261d6e
RESEARCH PRODUCT
Synthesis and Characterization of Yttrium Complexes Containing a Tridentate Linked Amido−Cyclopentadienyl Ligand
Thomas P. SpaniolJun OkudaKai C. Hultzschsubject
Inorganic ChemistryDilithiumchemistry.chemical_compoundCyclopentadienyl complexStereochemistryChemistryLigandOrganic Chemistrychemistry.chemical_elementYttriumPhysical and Theoretical ChemistryMedicinal chemistrydescription
The reaction of dilithium salts of the tridentate linked amido−cyclopentadienyl ligands Li2(C5Me4SiMe2NCH2CH2X) (X = OMe, NMe2, CH2OMe) with [Y(o-C6H4CH2NMe2)Cl2(LiCl)(THF)4] and Y(η5-C5H5)Cl2(THF)3 give chloro-bridged ate complexes of the type [Li(THF)][Y(η5:η1-C5Me4SiMe2NCH2CH2X)(R)Cl], where R = o-C6H4CH2NMe2, η5-C5H5.
year | journal | country | edition | language |
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1998-02-01 | Organometallics |