6533b7d4fe1ef96bd1262082

RESEARCH PRODUCT

A decacobalt(ii) cluster with triple-sandwich structure obtained by partial reductive hydrolysis of a pentacobalt(ii/iii) Weakley-type polyoxometalate.

Juan M. Clemente-juanEugenio CoronadoJosé Luis García FierroYan DuanCarlos Giménez-saiz

subject

010405 organic chemistryChemistryInorganic chemistryMetals and AlloysGeneral ChemistryType (model theory)010402 general chemistry01 natural sciencesCatalysis0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsHydrolysisCrystallographyOctahedronPolyoxometalateMaterials ChemistryCeramics and CompositesCluster (physics)

description

Partial reductive hydrolysis of a penta-CoII/III cluster [CoII4(H2O)2(CoIIIW9O34)(PW9O34)]12− (1) leads to the formation of [Co2{Co3(H2O)(Co(OH)2W7O26)(PW9O34)}2]22− (2). This polyoxometalate is made up of two capping [PW9O34]9− units and two bridging [W7O26]10− units that assemble to encapsulate a novel deca-CoII cluster core comprising octahedral and tetrahedral CoII ions.

yearjournalcountryeditionlanguage
2016-11-04Chemical communications (Cambridge, England)
10.1039/c6cc05485dhttps://pubmed.ncbi.nlm.nih.gov/27774535