6533b7d4fe1ef96bd12631a9
RESEARCH PRODUCT
Enzymatically catalyzed synthesis of photocrosslinkable oligophenols
Matthias H. ReihmannHelmut Rittersubject
Polymers and PlasticsbiologyOrganic ChemistryCondensed Matter PhysicsOligomerCatalysisEnzyme catalysischemistry.chemical_compoundchemistryPhotosensitivityPolyphenolPolymer chemistryMaterials ChemistryAcetonebiology.proteinOrganic chemistryPhenolsPhysical and Theoretical ChemistryPeroxidasedescription
The HRP-catalyzed oligomerization of cinnamoyl-hydroquinone-ester and cinnamoyl-4-hydroxyanilide led to the formation of soluble polyphenols. The oligomers were synthexized in water/1,4-dioxane and in water/acetone mixtures and characterized by NMR, FTIR and SEC. Upon UV treatment of the homogenoes films the polyphenols were crosslinked due to [2+2]-cycloadditions of the cinnamoyl functions.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2000-09-01 | Macromolecular Chemistry and Physics |