6533b7d4fe1ef96bd1263367
RESEARCH PRODUCT
Helical supramolecular polymerization of C3-symmetric amides and retroamides: on the origin of cooperativity and handedness.
Fátima GarcíaLuis SánchezJulia BuendíaPedro M. ViruelaJuan AragóEnrique OrtíJoaquín Calbosubject
010405 organic chemistryStereochemistryMetals and AlloysSupramolecular chemistryAbsolute configurationCooperativityGeneral Chemistry010402 general chemistry01 natural sciencesCatalysis0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsStereocenterchemistry.chemical_compoundCrystallographychemistryPolymerizationAmideMaterials ChemistryCeramics and CompositesSide chaindescription
The cooperative supramolecular polymerization of 1 and 2 yields P- or M-type helical aggregates depending on the absolute configuration (S or R) of the stereogenic centres attached to the side chains. The connectivity of the amide group does not affect the handedness of the helical aggregates, but determines a larger cooperativity for retroamides 1.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2016-05-05 | Chemical communications (Cambridge, England) |