6533b7d5fe1ef96bd1263c13

RESEARCH PRODUCT

Standard addition method in FIA. Comparison between different assemblies

Pilar Campíns-falcóFrancisco Bosch-reigF. Blasco-gómez

subject

Flow injection analysisChemistryAnalytical chemistryBiochemistryChlorideAnalytical Chemistrychemistry.chemical_compoundStandard additionReagentmedicineEnvironmental ChemistryChlorophenol redSpectroscopyAnalysis methodmedicine.drug

description

A comparison between the different proposed methods to perform the standard addition in an on-line way (flow injection analysis) is made. The different assemblies (reverse and conventional FIA) and the employed standards in every method are compared. Three analyses were carried out, two of them were analyses of samples of pH indicators (methylorange and chlorophenol red) prepared at an acid pH, while the standards were prepared at a basic pH. The third analysis was the analysis of chloride in different synthetic waters with a perfectly known composition for all the ions present in the samples. Besides a new method to perform the on-line standard addition is proposed, trying to reduce the consumption of reagents and sample. This new method makes use of a 6-port multiposition valve electrically actuated.

https://doi.org/10.1016/s0003-2670(98)00658-8