6533b7d5fe1ef96bd1264571
RESEARCH PRODUCT
Alkylation of Benzene with Short-Chain Olefins over MCM-22 Zeolite: Catalytic Behaviour and Kinetic Mechanism
A. CormaV. Martínez-soriaE. Schnoeveldsubject
PropeneReaction conditionschemistry.chemical_compoundchemistryPhysical and Theoretical ChemistryAlkylationSelectivityZeoliteKinetic energyPhotochemistryBenzeneCatalysisCatalysisdescription
Abstract Benzene alkylation with ethene and propene has been carried out under liquid-phase reaction conditions over zeolites MCM-22, Beta, and ZSM-5. MCM-22 seems to be a good catalyst for benzene alkylation especially with propene, showing high activity and stability and good selectivity. Kinetic experiments show that alkylation with propene follows an Eley–Rideal type mechanism.
year | journal | country | edition | language |
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2000-05-01 | Journal of Catalysis |