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RESEARCH PRODUCT
Nucleophilic iodonium interactions (NIIs) in 2-coordinate iodine(i) and silver(i) complexes
Antonio FronteraJas S. WardKari Rissanensubject
010405 organic chemistryChemistryChemical shiftMetals and Alloyschemistry.chemical_elementGeneral Chemistry010402 general chemistryIodine01 natural sciencesCatalysis0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsNucleophileComputational chemistryMaterials ChemistryCeramics and Compositesdescription
The generality of nucleophilic iodonium interactions (NIIs) has been demonstrated by preparing a range of silver(i) and iodonium (I+) complexes and studying their 15N NMR chemical shifts, with the first example of a NII-complex involving a 2-coordinate silver(i) complex being confirmed by X-ray crystallography, and its nucleophilicity studied by DFT calculations.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2021-04-27 | Chemical Communications |