6533b7d5fe1ef96bd1265229
RESEARCH PRODUCT
Isotope shift and hyperfine structure of stable platinum isotopes
Walter NeuR. WinklerH.-j. KlugeG. SawatzkyGerd Passlersubject
Materials scienceDye laserIsotopeAnalytical chemistrychemistry.chemical_elementElectronic structureAtomic and Molecular Physics and OpticsMolecular electronic transitionNuclear magnetic resonancechemistryKinetic isotope effectNuclear Physics - ExperimentSpectroscopyPlatinumHyperfine structuredescription
Isotope shift (IS) and hyperfine structure (hfs) measurements have been performed on seven lines of the platinum I spectrum with interference as well as laser fluorescence spectroscopy. In the latter case a frequency-doubled single-mode cw dye laser was applied. The IS of190Pt with a natural abundance of only 0.01% was determined to beδν 190, 192=−38.65(8) mK in theλ306.47 nm transition. The IS parameters and the effective hfs integrals in the configuration (5d+6s)10 were determined in intermediate coupling by a least squares fit of the IS and hfs data with eigenvectors obtained from the platinum fine structure (fs). The results are compared with theoretical values and yield improvedδ〈r 2〉 data.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1987-06-01 |