6533b7d5fe1ef96bd126531d
RESEARCH PRODUCT
Observation of electroluminescence at room temperature from a ruthenium(II) bis-terpyridine complex and its use for preparing light-emitting electrochemical cells.
Pablo GaviñaHenk J. BolinkLuca CappelliEugenio Coronadosubject
Inorganic Chemistrychemistry.chemical_compoundchemistryLigandchemistry.chemical_elementPhysical and Theoretical ChemistryTerpyridineElectroluminescenceLuminescencePhotochemistryRed ColorElectrochemical cellRutheniumdescription
A terpyridine ruthenium (II) complex containing a substituted and an unsubstituted terpyridine ligand was synthesized, and its luminescence properties were studied in a solid-state single-layer light-emitting electrochemical cell. The obtained devices emitted light of a very deep red color (CIE, x = 0.717 y = 0.282) at low external applied bias. It is the first example of an electroluminescence device based on a bis-chelated ruthenium complex. Its ambient atmosphere decay is remarkably different from analogous devices using tris-chelated ruthenium complexes.
year | journal | country | edition | language |
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2005-07-27 | Inorganic chemistry |