6533b7d6fe1ef96bd1265a43

RESEARCH PRODUCT

A Study of the Separation of 1-Dodecene and 1-Tetradecene Hydroformylation Products in Aqueous Medium

Wilhelm Jan Tic

subject

Process Chemistry and TechnologyGeneral Chemical EngineeringButanolSodium dodecylbenzenesulfonateAqueous two-phase systemFiltration and SeparationGeneral ChemistryCatalysischemistry.chemical_compoundchemistryOrganic chemistry1-DodeceneMicroemulsionPhosphineHydroformylation

description

Abstract Experimental results of the solubilization of olefins in hydroformylation model systems, comprising 1-dodecene and 1-tridecanal or 1-tetradecene and 1-pentadecanal, water, butanol, sodium dodecylsulfate (SDS), sodium dodecylbenzenesulfonate (SDBS), and/or tri(m-sulfofenyl)phosphine trisodium salt (TPPTS-Na) are presented. The selected systems were used for the hydroformylation of 1-dodecene and 1-tetradecene whereby high yields of aldehydes were obtained. After the reaction, the mixture spontaneously separated into an organic phase with the reaction products and an aqueous phase comprising the catalyst and excess phosphine ligand.

yearjournalcountryeditionlanguage
2009-07-31Separation Science and Technology
https://doi.org/10.1080/01496390903017436