6533b7d6fe1ef96bd1265a8e

RESEARCH PRODUCT

Trimethylplatinum(IV) complexes with ON bidentate ligands

Vincenzo RomanoFrancesco MaggioT. PizzinoR. Badalamenti

subject

DenticityStereochemistryChemistryMonobasic acidOrganic ChemistryBiochemistryMagnetic susceptibilityInorganic ChemistryNMR spectra databaseMetalvisual_artPolymer chemistryMaterials Chemistryvisual_art.visual_art_mediumMoietyPhysical and Theoretical Chemistry

description

Abstract Complexes of the trimethylplatinum(IV) moiety with bidentate monobasic salicylaldimines C 6 H 5 (OH)CHNR (R = ethyl, propyl, phenyl) have been prepared and characterized by IR, UV and NMR spectra and magnetic susceptibility measurements. The complexes are dimeric with double PtOPt bridges, and the metal appears to be pseudo-octahedrally hexacoordinated.

https://doi.org/10.1016/s0022-328x(00)81847-1