6533b7d6fe1ef96bd1265ab9
RESEARCH PRODUCT
Synthesis of optically pure alkynols
M. SteigerwaldH. SingerTh. KünstlerDieter Schollmeyersubject
Recrystallization (geology)EthanolOrganic ChemistryDiastereomerCatalysisInorganic ChemistryHexanechemistry.chemical_compoundchemistryValineOrganic chemistryPhysical and Theoretical ChemistryAliphatic compoundSaponificationdescription
Abstract (R,S)-1-alkylprop-2-yn-1-ols have been separated by a 2-step procedure, esterification with N-p-tosyl-(L)-phenylalanine (or valine), recrystallisation of the diastereomeric esters from ethanol/hexane and saponification of the optically pure esters.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1993-07-01 | Tetrahedron: Asymmetry |