6533b7d6fe1ef96bd1265ac3

RESEARCH PRODUCT

Alkyl Complexes of Group 4 Metals Containing a Tridentate-Linked Amido−Cyclopentadienyl Ligand:  Synthesis, Structure, and Reactivity Including Ethylene Polymerization Catalysis

Angelika ButtFrancisco AmorKaren E. Du PlooyThomas P. SpaniolJun Okuda

subject

chemistry.chemical_classificationChemistryLigandOrganic ChemistryMedicinal chemistryCatalysisInorganic ChemistryMetalCyclopentadienyl complexEthylene polymerizationGroup (periodic table)visual_artvisual_art.visual_art_mediumOrganic chemistryReactivity (chemistry)Physical and Theoretical ChemistryAlkyl

description

A series of group 4 metal complexes M(η5:η1:η1-C5Me4SiMe2NCH2CH2X)R2 (M = Ti; R = Me, CH2Ph; M = Zr, Hf; R = Me, Et, nPr, nBu, CH2Ph, CH2SiMe3, Ph) containing the tridentate-linked amido−tetramethy...

https://doi.org/10.1021/om980722n