6533b7d6fe1ef96bd1265c89
RESEARCH PRODUCT
First Magnetostructural Study on a Heterodinuclear 2,2′-Bipyrimidine-Bridged Complex
Miguel JulveGiovanni De MunnoJuan FausDonatella ArmentanoJoan CanoFrancesc LloretJosé Martínez-lilloJosé Martínez-lillosubject
Inorganic ChemistryMetalCrystallographyNickelFerromagnetismStereochemistryChemistryLigandvisual_artIntramolecular forcevisual_art.visual_art_mediumchemistry.chemical_elementPhysical and Theoretical Chemistrydescription
The use of the [ReCl(4)(bpym)] precursor as a ligand toward the fully solvated nickel(II) metal ion affords the first example of a 2,2'-bipyrimidine-bridged Re(IV)-Ni(II) complex, [ReCl(4)(μ-bpym)NiBr(2)(H(2)O)(2)] (1), whose intramolecular ferromagnetic coupling has been substantiated from both experimental and theoretical studies.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2011-11-19 | Inorganic Chemistry |