6533b7d6fe1ef96bd1266f19

RESEARCH PRODUCT

Alkene epoxidations catalysed by Mo(VI) supported on Merrifield's polymer

A ZapaterV. SanzSalvador GilRamon MestresR Gonzalez

subject

chemistry.chemical_classificationPolymers and PlasticsAlkeneGeneral Chemical EngineeringCatalyst supportEpoxideGeneral ChemistryBiochemistryEnolCatalysischemistry.chemical_compoundchemistryPolymer chemistryMaterials ChemistryEnvironmental ChemistrySelectivityCycloalkeneAmination

description

High conversion and epoxide selectivity from alkenes is achieved with tert-butyl hydroperoxide and a polystyrene-grafted Mo(VI) catalyst, with no noticeable leaching of Mo from the support.

https://doi.org/10.1016/s1381-5148(98)00056-x