6533b7d6fe1ef96bd1266f23

RESEARCH PRODUCT

Bellbergite?a new mineral with the zeolite structure type EAB

B. RüdingerG. HentschelEkkehart Tillmanns

subject

CrystallographyGeophysicsOxygen atomMineralGeochemistry and PetrologyChemistryEmpirical formulaSpace groupMineralogyXenolithStructure typeCrystal structureZeolite

description

The new mineral bellbergite, (K, Ba, Sr)2Sr2Ca2(Ca, Na)4Al18Si18O72 · 30H2O, has been found in Ca-rich xenoliths at the Bellberg volcano near Mayen, Eifel, Germany. It occurs as well formed bipyramids with a length up to 0.3 mm. Possible space groups are P63/mmc, P62c and P63mc with a = 13.244(1) A, c = 15.988(2) A, V = 2429 A3, Z = 1. The density is: Dm, = 2.20(2) Mg/m3, Dc = 2.19 Mg/m3. The empirical formula based on 72 oxygen atoms is: Ba0.26Na0.72K1.33Sr2.36Ca5.32Al17.55Si18.36O72 · 30H2O. The mineral is uniaxial negative with ω = 1.522(2) and e = 1.507(2) (λ = 589 nm). The strongest lines in the X-ray powder pattern are (d (A), I, hkl): 3.80 (100) (300, 212, 104), 6.58 (80) (102), 2.95 (70) (312, 214), 2.21 (70) (330), 2.70 (50) (402), 2.50 (50) (410, 314), 1.83 (50) (416). The crystal structure corresponds to the zeolite structure type EAB.

https://doi.org/10.1007/bf01163093