6533b7d6fe1ef96bd12670ac
RESEARCH PRODUCT
A novel mixed valent Cu(II)-Cu(I) 2D framework made of a hydrazone and μ-SCN bridged metallacyclic loops cross-linked by μ3-SCN chains.
Corrado RizzoliDipali SadhukhanCarlos J. Gómez-garcíaLoïc J. CharbonnièreEugenio GarribbaAkram Yahia-ammarSamiran Mitrasubject
chemistry.chemical_classificationIonsCopper complexStereochemistryPyridinesHydrazonesMolecular ConformationTemperatureHydrazoneCrystallography X-RayLigandsInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryMixed valentCoordination ComplexesHydrazone ligandMethyleneCopperdescription
A mixed valent copper complex [Cu(II)Cu(I)(L)(μ-SCN)(μ(3)-SCN)](n) (LH = N'-((pyridin-2-yl)methylene)acetohydrazide) has been synthesized and characterized. It is a unique example of a 2D mixed valent Cu(II)-Cu(I) interlinked molecular assembly with a very unusual bridging property of the hydrazone ligand. An extraordinary in situ partial Cu(II)→ Cu(I) reduction is observed in this system at room temperature.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2012-08-30 | Dalton transactions (Cambridge, England : 2003) |