6533b7d6fe1ef96bd12670d2

RESEARCH PRODUCT

2-(Naphthalen-1-yl­amino)­cyclo­hexa­nol

Rachid OutouchLarbi El FirdoussiMustapha Ait AliBrahim BoualyCorrado Rizzoli

subject

HeptaneChemistryHydrogen bondCyclohexane conformationGeneral ChemistryCondensed Matter PhysicsRing (chemistry)HEXAOrganic PapersCatalysisCrystallcsh:ChemistryCrystallographychemistry.chemical_compoundlcsh:QD1-999General Materials Science

description

The title compound, C16H19NO, was synthesized under solvent-free conditions by reaction of 7-oxa-bicyclo[4.1.0]heptane and naphthalen-1-amine in the presence of Ca(CF3COO)2 as catalyst. The cyclohexane ring adopts a chair conformation. In the crystal, molecules are linked by intermolecular N—H...O hydrogen bonds and C—H...π interactions into chains parallel to the c axis.

10.1107/s1600536811021714http://europepmc.org/articles/PMC3152018