6533b7d6fe1ef96bd1267143
RESEARCH PRODUCT
NMR enantiodifferentiation of triphenylphosphonium salts by chiral hexacoordinated phosphate anions
Sylvain JugéAnne Laurence LondezJérôme LacourVirginie HebbeCatherine Goujon-ginglingerJacques UzielFranck Meyersubject
Phosphonium saltsBINPHATChiral anionsOrganic ChemistryTRISPHATPhosphateBiochemistryStereocenterchemistry.chemical_compoundNMR enantiodifferentiationTRISPHATchemistryReagentddc:540Drug DiscoveryAmino acids and derivativesOrganic chemistrydescription
BINPHAT anion—rather than TRISPHAT—is an efficient NMR chiral shift reagent for triphenylphosphonium salts containing stereogenic centers on the aliphatic side-chain. BINPHAT—rather than TRISPHAT—anion is an efficient NMR (1H and 31P) chiral shift reagent for chiral triphenylphosphonium salts.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2003-03-01 | Tetrahedron Letters |