The product of a regiospecific and stereoselective ene-reaction of a polycyclic terpenoid system

6533b7d7fe1ef96bd12678f0

RESEARCH PRODUCT

The product of a regiospecific and stereoselective ene-reaction of a polycyclic terpenoid system

Carmen Ramírez De Arellano Ana C. Cuñat Ismael Navarro Antonio Abad Consuelo Agulló

subject

Crystal Chemistry Stereochemistry Product (mathematics)Intermolecular force General Materials Science Stereoselectivity General Chemistry Condensed Matter Physics Terpenoid Ene reaction

description

The X-ray structure of dimethyl (Z)-[(8aS,2R,4aR,4bR)-8a-methoxycarbonyl-1,4a,7-trimethyl-8-oxo-2,3,4,4a,4b,5,8,8a,9,10-decahydrophenanthren-2-yl]-2-butenedioate, C25H32O7, confirmed its relative configuration. The structure shows the bend in the molecular skeleton as found for similar compounds. Weak intermolecular C—H⋯O interactions have been found in the crystal.

year	journal	country	edition	language
2001-05-31	Acta Crystallographica Section E Structure Reports Online

https://doi.org/10.1107/s1600536801008510

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