6533b7d7fe1ef96bd1267965

RESEARCH PRODUCT

Multilayer Thin Films by Layer-by-Layer Assembly of Hole- and Electron-Transport Polyelectrolytes: Optical and Electrochemical Properties

Kyungsun ChoiRudolf Zentel

subject

chemistry.chemical_classificationConductive polymerPhotoluminescenceMaterials sciencePolymers and PlasticsOrganic ChemistryLayer by layerPolymerCondensed Matter PhysicsPolyelectrolytechemistryPolymer chemistryMaterials ChemistrySelf-assemblyPhysical and Theoretical ChemistryThin filmSpectroscopy

description

In this paper, we pressent the synthesis of a series of p-type and n-type semicondnctring polyelectrolytes with triarylamine, oxadiazole, thiarliazole and triazine moictes. The synthesized polymeric hole and electrom iransport materials were examined optically and electrochemically using UV/Vis spectroscopy. PL spectroscopy and CV. Based on the optical and electrochemical data, each of the energy levels were calculated and all values suggested that the were promising hole-(p-type) or alectron=transprot (n-type) materials for devices. Moreover, the synthesized ionie polymers were suitable for LBL thin film deposition from ditute polymer solutions and the multilayers were fully characterized by UV/Vis. PL spectroscopy and CV.

https://doi.org/10.1002/macp.200600361