6533b7d7fe1ef96bd1267996
RESEARCH PRODUCT
Synthesis and characterisation of tetrazole compounds: 3 series of new ligands representing versatile building blocks for iron(II) spin-crossover compounds
C. Matthias GrunertC. Matthias GrunertJohannes SchweiferPeter WeinbergerChristina HampelWolfgang LinertKurt MereiterArno F. StassenArno F. Stassensubject
chemistry.chemical_classificationOrganic ChemistrySupramolecular chemistrySpin transitionCrystal structurePolymerNuclear magnetic resonance spectroscopyAnalytical ChemistryInorganic Chemistrychemistry.chemical_compoundCrystallographychemistrySpin crossoverTetrazoleSingle crystalSpectroscopydescription
Abstract New tetrazole compounds were synthesized and characterised by NMR and FTIR spectroscopy as well as by single crystal X-ray diffraction. We present in this paper mono- and ditetrazoles, which represent a versatile class of building blocks for the formation of mononuclear iron(II) complexes with monotetrazoles as terminal ligands as well as iron(II) coordination polymers with ditetrazoles as bridging ligands. Especially, the series of α,ω-bis[tetrazol-1-yl]-alkanes open the field of fascinating supramolecular structures with spin transition properties.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2005-01-01 | Journal of Molecular Structure |