6533b7d7fe1ef96bd1267b72
RESEARCH PRODUCT
Supercritical Carbon Dioxide: A Promoter of Carbon-Halogen Bond Heterolysis
Andrea OlmosRossella MelloAna CaballeroGregorio AsensioJaime Martínez-ferrerPedro J. PérezMaría Elena González-núñezThais Delgado-abadsubject
Halogen bondSupercritical carbon dioxideChemistrychemistry.chemical_elementGeneral ChemistryGeneral MedicineCarbocationPhotochemistryHeterolysisCatalysisSupercritical fluidSolventSolvent effectsCarbondescription
as the leaving groupdeparts from the carbon atom prior to the entrance of thenucleophile. Polar protic solvents with high dielectric con-stants promote polar bond heterolysis by providing effectiveH-bonding and electron-pair donation interactions to theleaving group and the incipient carbocation, respectively.Then, the solvent captures the carbocation intermediate togive the corresponding S
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2013-10-15 | Angewandte Chemie |