6533b7d7fe1ef96bd126833a

RESEARCH PRODUCT

Hairy Aramide Rod−Coil Copolymers

Helga SeylerAndreas F. M. Kilbinger

subject

chemistry.chemical_classificationPolymers and PlasticsHydrogen bondOrganic ChemistryDispersityConjugated systemInorganic Chemistrychemistry.chemical_compoundchemistryDynamic light scatteringPolymer chemistryMaterials ChemistrySide chainCopolymerEthylene glycolAlkyl

description

We have synthesized monodisperse “hairy rod oligomers” based on oligo(p-benzamide)s carrying alkyl side chains and conjugated them with polydisperse poly(ethylene glycol) (PEG) chains. The well-defined oligomers were synthesized from 4-amino-2-hexyloxybenzoic acid using a commercial peptide synthesizer. The PEG conjugated hairy rod−coil block copolymers self-assemble in polar and nonpolar organic solvents. The self-organization in solution was investigated by dynamic light scattering (DSL) and transmission electron microscopy (TEM) as a function of solvent, equilibration time, and polarity of the substrate. Individual fibers and fiberlike bundles of aggregates could be observed. As all hydrogen bond donors are intramolecularly saturated in these aramide oligomers, we propose π-stacking as the aggregation mechanism for this novel class of substituted oligoaramides. NMR studies on a model compound support this assumption.

yearjournalcountryeditionlanguage
2010-06-04Macromolecules
https://doi.org/10.1021/ma100230z