6533b7d7fe1ef96bd1268508

RESEARCH PRODUCT

Free-standing smectic LC elastomer films

R. KöhlerU. DietrichMathias LöscheC. TolksdorfRudolf ZentelRalf Stannarius

subject

chemistry.chemical_classificationDiffractionMaterials scienceFilm planeMesophasePolymerElastomerlaw.inventionchemistryOptical microscopelawPhase (matter)Composite materialLayer (electronics)

description

ABSTRACTWe probe the mesophase transitions and layer structures in thin ordered smectic liquid crystalline elastomer films by means of x-ray diffraction and optical microscopy. Oriented elastomer films of submicrometer thickness are produced by crosslinking freely suspended smectic polymer films. After crosslinking, the mesomorphism is similar to that of the precursor polymer. Smectic layers align parallel to the film plane. The layer spacing increases with temperature in the SmC* phase while it decays above the SmC*-SmA transition.

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