Ferromagnetic coupling in a one-dimensional molecular railroad copper(II) azido compound containing a defective double cubane motif.

6533b7d7fe1ef96bd1268559

RESEARCH PRODUCT

Ferromagnetic coupling in a one-dimensional molecular railroad copper(II) azido compound containing a defective double cubane motif.

Francesc Lloret Miao Du Lei Zhang Miguel Julve Ji-tao Wang Liang-fu Tang Zhi-hong Wang

subject

chemistry.chemical_classification Stereochemistry chemistry.chemical_element Polymer Copper Ion Inorganic Chemistry Coupling (electronics)chemistry.chemical_compound Crystallography chemistry Ferromagnetism Cubane Physical and Theoretical Chemistry

description

The compound [Cu2(bpm)2(N3)4]n (bpm = bis(pyrazol-1−yl)methane) shows three unique coordination modes (μ1,1-, μ1,1,1-, μ1,1,3-N3) and ferromagnetic interaction between the copper(II) ions. The structure of the compound exhibits a one-dimensional railroad polymer made up of repeating defective dicubane-type units linked by μ1,1,3-N3 bridges.

year	journal	country	edition	language
2001-06-26	Inorganic chemistry

10.1021/ic001406f https://pubmed.ncbi.nlm.nih.gov/11421715

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