6533b7d7fe1ef96bd1268f6a

RESEARCH PRODUCT

Oligophenyls with Multiple Disulfide Bridges as Higher Homologues of Dibenzo[c,e][1,2]dithiin: Synthesis and Application in Lithium-Ion Batteries.

Dieter SchollmeyerChristopher P. EnderChristoph SonnenscheinFaxing WangXinliang FengAkimitsu NaritaKlaus Müllen

subject

dibenzo[12]dithiinoligophenylspolycyclesCommunicationOrganic Chemistrylithium-ion batteriesSulfur Heterocycles | Hot Paperchemistry.chemical_elementGeneral ChemistryCatalysisCathodeCommunicationssulfur heterocyclesIonlaw.inventionCrystallographychemistrylawLithiumEnantiomerCurrent density

description

Abstract Higher homologues of dibenzo[c,e][1,2]dithiin were synthesized from oligophenyls bearing multiple methylthio groups. Single‐crystal X‐ray analyses revealed their nonplanar structures and helical enantiomers of higher meta‐congener 6. Such dibenzo[1,2]dithiin homologues are demonstrated to be applicable to lithium‐ion batteries as cathode, displaying a high capacity of 118 mAh g−1 at a current density of 50 mA g−1.

yearjournalcountryeditionlanguage
2020-06-05Chemistry (Weinheim an der Bergstrasse, Germany)
10.1002/chem.202000728https://pubmed.ncbi.nlm.nih.gov/32202685