6533b7d8fe1ef96bd1269780

RESEARCH PRODUCT

ChemInform Abstract: 1,4-Regioselective Iodofunctionalizations of 1,3-Butadiene.

José BarluengaJosé M. GonzálezPedro J. CamposGregorio Asensio

subject

chemistry.chemical_compoundTetrafluoroborateAqueous solutionchemistryRegioselectivity13-ButadieneGeneral MedicineAcetonitrileBenzeneMedicinal chemistry

description

1,3-Butadiene (I) is treated with a iodonium tetrafluoroborate in the presence of HBF4 and aqueous acetonitrile (II) or benzene (IV), yielding the 1,4-adducts (III) or (V).

https://doi.org/10.1002/chin.198924135