6533b7d8fe1ef96bd1269799

RESEARCH PRODUCT

ChemInform Abstract: Photoelectrochemical Study of Electrochemically Formed Semiconducting Yttrium Hydride (YH3-x).

Salvatore PiazzaCarmelo SunseriM. C. RomanoF. Di Quarto

subject

In situMetalPhotocurrentHydrideBand gapEtching (microfabrication)Chemistryvisual_artPhase (matter)visual_art.visual_art_mediumAnalytical chemistryGeneral MedicineSpectroscopy

description

Abstract The first photoelectrochemical study of semiconducting YH 3− x films formed by etching bulk Y metal in 0.5 M H 2 SO 4 solution is reported. The formation of semiconducting hydride having an indirect optical band gap, E g opt , of about 2.35 eV is confirmed by in situ photocurrent spectroscopy. The photoelectrochemical behaviour of such a phase was investigated both in alkaline and in acidic solutions. The flat band potential was estimated to be U fb =−1.25 V/NHE, independent of pH.

https://doi.org/10.1002/chin.199944024