6533b7d8fe1ef96bd12697ff
RESEARCH PRODUCT
First Annelated Azaphosphole-Ferrocenes: Synthetic Pathways and Structures
Vincent RampazziNadine PirioAleksandr N. KostyukJean-cyrille HiersoHélène CatteyA. P. MarchenkoHeorgii N. KoidanAnastasiya Hurievasubject
Inorganic Chemistrychemistry.chemical_compoundFerroceneChemistryStereochemistryOrganic ChemistryPhysical and Theoretical ChemistryBackbone conformationMetallocenePlanarity testingdescription
The first annelated bis- and mono-3H-1,3-azaphosphole ferrocene sandwich compounds have been synthesized from aminoferrocenes, and their X-ray structures are compared to those of their selenide-protected P═Se analogues, showing net discrepancies both in metallocene backbone conformation and in fused-ring planarity.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2012-08-27 | Organometallics |