6533b7d8fe1ef96bd1269a0f

RESEARCH PRODUCT

Sesquiterpenes from Centaurea aspera

Juan F. Sanz-cerveraFélix SancenónJ. Alberto MarcoMiguel CardaAlberto Yuste

subject

LignanMolecular StructurebiologyStereochemistryCentaureaPlant ScienceGeneral MedicineHorticultureAsteraceaeSubspeciesSesquiterpenebiology.organism_classificationBiochemistryTerpenechemistry.chemical_compoundModels ChemicalchemistryChemotaxonomyCentaurea asperaBotanySesquiterpenesMolecular BiologyMatairesinol

description

Abstract The aerial parts of two subspecies of Centaurea aspera L. (Asteraceae) yielded the germacranolides 1a – h , 2 , 3 , 4 and 5 , the elemane derivatives 6d and 6f , the lignan matairesinol, the degraded terpene loliolide, and the onopordopicrin–valine dimeric adduct 7 . From these, compounds 1e , 3 and 6d are natural products. The chemical composition of the two subspecies is very similar, a circumstance which does not support a taxonomic subdivision of the species.

https://doi.org/10.1016/j.phytochem.2005.06.004