6533b7d8fe1ef96bd1269a36
RESEARCH PRODUCT
Isobaric vapor-liquid equilibrium of binary mixtures of 1-propanol + chlorobenzene and 2-propanol + chlorobenzene
Pablo J. MiguelVicenta González-alfaroFrancisco J. LlopisAna DejozM. Isabel Vázquezsubject
UNIQUACChemistryGeneral Chemical EngineeringGeneral Physics and AstronomyThermodynamicsMole fractionPropanolchemistry.chemical_compound1-PropanolChlorobenzeneNon-random two-liquid modelIsobaric processVapor–liquid equilibriumPhysical and Theoretical Chemistrydescription
Abstract Isobaric vapor-liquid equilibria were obtained for the system 1-propanol + chlorobenzene at 20 and 100 kPa and for the system 2-propanol + chlorobenzene at 100 kPa using a dynamic still. The experimental error in temperature was ±0.1 K, in pressure ±0.01 kPa and ±0.1 kPa for the experiments carried out at 20 and 100 kPa, respectively, and in the liquid and vapor mole fraction 0.001. The two systems satisfy the point-to-point thermodynamic consistency test. Both systems show a positive deviation from ideality. The data were well correlated with the Margules, Van Laar, Wilson, NRTL and UNIQUAC equations.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1997-06-01 |