6533b7d8fe1ef96bd1269b27

RESEARCH PRODUCT

A heteropentanuclear oxalato-bridged [ReIV 4GdIII] complex: synthesis, crystal structure and magnetic properties

José Martínez-lilloMiguel JulveJoan CanoLaura Cañadillas-delgadoFrancesc LloretJuan Faus

subject

StereochemistryChemistryMetals and AlloysGeneral ChemistryCrystal structureCatalysisAntiferromagnetic couplingSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsIonCrystallographyIntramolecular forceMaterials ChemistryCeramics and Composites

description

The compound (NBu 4) 5[Gd III{Re IVBr 4(μ-ox)} 4(H 2O)]·H 2O (1), with intramolecular antiferromagnetic coupling, is the first Re(iv) system incorporating a 4f ion. © 2012 The Royal Society of Chemistry.

http://hdl.handle.net/10261/73272