6533b7d8fe1ef96bd126a210
RESEARCH PRODUCT
false
Georg S. Greschnersubject
Quantitative Biology::BiomoleculesLaplace transformbusiness.industryChemistryGaussianNumerical analysisPhotometerLight scatteringlaw.inventionComputational physicsCondensed Matter::Soft Condensed MatterNonlinear systemsymbols.namesakeOpticslawPolymer chemistryEmpirical formulasymbolsMolar mass distributionbusinessdescription
The molecular weight distribution (MWD) of a high polymer is calculated from a weakly perturbed Zimm-plot of the classical light scattering on dilute solutions of Gaussian polymer coils (theta state). A typical Zimm-plot is simulated corresponding to the measurements of high accuracy as would be obtained by using the laser photometer described by Hack and Meyerhoff. The accuracy as published by these authors for small dissymmetries is used. Two numerical methods for calculating the MWD are briefly described and tested, both using an empirical formula for the Laplace image of the calculated MWD.
year | journal | country | edition | language |
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1982-05-14 | Die Makromolekulare Chemie |