6533b7d8fe1ef96bd126a217

RESEARCH PRODUCT

Thermostimulated processes in statically and dynamically disordered luminescent solids

I.a. Tale

subject

Aluminium oxidesCondensed matter physicsImpurityChemistryInorganic chemistryGeneral EngineeringCharge carrierActivation energyTrappingLuminescenceThermoluminescenceSpectral line

description

Abstract Trap spectra depending on the concentration of defects in crystalline KBr-T1, LiF-Mg, Ti, A1 2 O 3 and glassy Na 2 O·SiO 2 are investigated. The nature of inhomogeneous broadening and continuous distribution of traps over activation energies at sufficiently high defect concentrations is considered. Impurity hopping controlled recombination of electronic excitations is observed. The presence of enlarged values of process activation energies and frequency factors is discussed in terms of the concept of dynamic disorder, taking into account the fluctuational changes in both the perfectpart and the structure of defects in the solid at high temperatures.

https://doi.org/10.1016/1359-0189(93)90047-d