6533b7d8fe1ef96bd126b42a

RESEARCH PRODUCT

Alkane oxidation by a carboxylate-bridged dimanganese(III) complex

Gonzalo BlayI. FernándezT. GiménezJ. R. PedroR. RuizE. PardoF. LloretM. C. Muñoz

subject

Crystal-structuresUNESCO::QUÍMICA:QUÍMICA::Química orgánica [UNESCO]Escherichia-coliKetones:QUÍMICA [UNESCO]Manganese oxamatoDimerCarboxylate-bridged dimanganese complexFISICA APLICADAOxidationAlkanesManganese(iii)UNESCO::QUÍMICA::Química orgánicaCoreOxidation ; Carboxylate-bridged dimanganese complex ; Manganese oxamato ; Alkanes ; KetonesRibonucleotide reductaseMagnetic-properties

description

[EN] A new manganese( III) oxamato dimer possesing an unprecedented Mn-2(mu -O2CR)(mu -OH2. . .O2CR) core has been synthesised, structurally and magnetically characterised, and used as a catalyst for the oxidation of alkanes to alcohols and ketones by (BuO2H)-O-t and O-2 in CH2Cl2 at rt.

yearjournalcountryeditionlanguage
2001-01-01
http://hdl.handle.net/10550/18821