6533b7d8fe1ef96bd126b65d
RESEARCH PRODUCT
Electrochemical and bioelectrocatalytical properties of novel block-copolymers containing interacting ferrocenyl units
M.p.garcía ArmadaBeatriz AlonsoCarmen M. CasadoFrancisco-j. López-villanuevaJosé LosadaHolger Freysubject
chemistry.chemical_element02 engineering and technology010402 general chemistryElectrochemistry01 natural sciencesBiochemistryInorganic Chemistrychemistry.chemical_compoundPolymer chemistryMaterials ChemistryCopolymerGlucose oxidasePhysical and Theoretical Chemistrychemistry.chemical_classificationNicotinamidebiologyChemistryOrganic ChemistryPolymer021001 nanoscience & nanotechnology0104 chemical sciencesFerroceneElectrodebiology.protein0210 nano-technologyPlatinumdescription
The electrochemical characterization of three different polystyrene-b-polybutadiene block-copolymers, functionalized with diferrocenylsilane units, is reported. The PB-blocks have been functionalized with different fractions of electronicall y communicated, PSm-PB„ p (HSiMeFc2)p units, where m = 615, n = 53, p = 39 (1), m = 375, n = 92, p = 76 (2) and m = 455, n = 204, p = 170 (3). Electrochemical character ization has been carried out both in solution and after electrochemical deposition onto platinum electrodes. The bioelectrocatalytical properties of electrodes modified with the polymers in the nicotinamide dinucleotide (NADH) and glucose oxidase (GOx) oxidations have been investigated as a function of the constitution and structure of the polymers. The analytical properties of electrodes mod ified with these polymers as sensors of NADH and GOx are described. In addition, an amperometric biosensor for glucose, prepared by electrostatic immobilization of glucose oxidase onto a platinum electrode modified with one of the ferrocenyl block-copolymers as an example, has been developed.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2008-08-01 | Journal of Organometallic Chemistry |