6533b7d8fe1ef96bd126b7ab

RESEARCH PRODUCT

Transverse chemical interface detection with coherent anti-Stokes Raman scattering microscopy

Hervé RigneaultFranck BillardSophie BrustleinDavid Gachet

subject

Materials science[SPI.OPTI] Engineering Sciences [physics]/Optics / PhotonicBiomedical EngineeringSpectrum Analysis Raman01 natural sciencesSignalMolecular physics010309 opticsBiomaterialssymbols.namesakeNarrowbandOptics0103 physical sciencesMicroscopyComputer SimulationCoherent anti-Stokes Raman spectroscopy010306 general physicsMicroscopyFormamidesbusiness.industryDimethylformamideSignal Processing Computer-AssistedAtomic and Molecular Physics and OpticsElectronic Optical and Magnetic MaterialsTransverse plane[SPI.OPTI]Engineering Sciences [physics]/Optics / Photonicsymbols[ SPI.OPTI ] Engineering Sciences [physics]/Optics / PhotonicbusinessRaman spectroscopyBeam (structure)Raman scattering

description

International audience; Transverse "chemical" interfaces are revealed with a conventional two beam narrowband coherent anti-Stokes Raman scattering microscopy setup in a collinear configuration. The exciting "pump" and "Stokes" beams are focused on the sample in two opposite directions. The subtraction of the two generated anti-Stokes signals gives rise to a signal that is directly proportional to the pure Raman spectrum of the resonant medium. This property is used to highlight an interface between glass and N,N-dimethylformamide (DMF) and recover the pure Raman spectrum of DMF around its 1408 cm−1 vibrational band.

https://doi.org/10.1117/1.3606574