Unusual phosphine oxidation: new triazolopyridyl-quinolyl phosphine oxide fluorescent dyes

6533b7d9fe1ef96bd126ba38

RESEARCH PRODUCT

Unusual phosphine oxidation: new triazolopyridyl-quinolyl phosphine oxide fluorescent dyes

Rafael Ballesteros Enrique García-españa Belén Abarca Françoise Colobert Frédéric R. Leroux Rafael Ballesteros-garrido Rafael Ballesteros-garrido

subject

Phosphine oxide 010405 organic chemistry [CHIM.ORGA]Chemical Sciences/Organic chemistry General Chemical Engineering Phosphorus chemistry.chemical_element General Chemistry 010402 general chemistry Photochemistry 01 natural sciences Nitrogen Fluorescence 3. Good health 0104 chemical sciences chemistry.chemical_compound chemistry Química orgànica Lone pair Phosphine Special geometry ComputingMilieux_MISCELLANEOUS

description

3-(2-Pyridyl)-[1,2,3]triazolo[1,5-a]quinolylphosphines suffer an unusual phosphine oxidation due to their special geometry that allows a s-donation of the nitrogen (N1) lone pair to phosphorus. This family of compounds behaves as strong fluorophores with high quantum yields.

year	journal	country	edition	language
2015-01-01

10.1039/c5ra04386g https://hal.archives-ouvertes.fr/hal-03004215

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