6533b7d9fe1ef96bd126ce33

RESEARCH PRODUCT

4,4′-bis(dimethylamino)biphenyl containing binding sites. A newfluorescent subunit for cation sensing

Ana M. CosteroRamón Martínez-máñezElena MonrabalFélix SancenónJuan SotoRosario Andreu

subject

inorganic chemicalsBiphenylFluorophoreStereochemistryProtein subunitGeneral ChemistryAlkali metalFluorescenceMedicinal chemistrychemistry.chemical_compoundchemistryCovalent bondBinding siteAcetonitrile

description

The emission behaviour of the 4,4′-bis(dimethylamino)biphenyl subunit covalently attached to aza-crown ethers is studied. Some new ligands have been synthesised in order to test the properties of this new fluorophore. The fluorescence of these new ligands and some other compounds previously described has been studied in acetonitrile in the presence of Ni2+, Cu2+, Zn2+, Hg2+, Pb2+, Cd2+ and also in the presence of some alkali and alkaline-earth cations.

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