6533b7d9fe1ef96bd126d577
RESEARCH PRODUCT
Vapor–liquid equilibrium of binary mixtures of chlorobenzene with 3-methyl-1-butanol, 3-methyl-2-butanol and 2-methyl-2-butanol, at 100 kPa
M. Isabel VázquezFrancisco J. LlopisAna DejozVicenta González-alfaroPablo J. Miguelsubject
UNIQUACChemistryGeneral Chemical EngineeringButanolGeneral Physics and AstronomyThermodynamicsMole fractionchemistry.chemical_compoundChlorobenzeneNon-random two-liquid modelIsobaric processVapor–liquid equilibriumPhysical and Theoretical Chemistry2-Butanoldescription
Abstract Isobaric vapor–liquid equilibria have been obtained for the systems 3-methyl-1-butanol+chlorobenzene, 3-methyl-2-butanol+chlorobenzene and 2-methyl-2-butanol+chlorobenzene at 100 kPa, using a dynamic still. The experimental error in temperature is ±0.1 K, in pressure ±0.1 kPa, and in the liquid and vapor mole fraction ±0.001. The three systems satisfy the point-to-point thermodynamic consistency test. All the systems show positive deviations from ideality. The data have been correlated with the Margules, Van Laar, Wilson, NRTL and UNIQUAC equations.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1998-12-01 | Fluid Phase Equilibria |