ChemInform Abstract: Oppenauer Oxidation of Secondary Alcohols with 1,1,1-Trifluoroacetone as Hydride Acceptor.

6533b7d9fe1ef96bd126d65b

RESEARCH PRODUCT

ChemInform Abstract: Oppenauer Oxidation of Secondary Alcohols with 1,1,1-Trifluoroacetone as Hydride Acceptor.

María Elena González-núñez Gregorio Asensio Jaime Martínez-ferrer Rossella Mello

subject

chemistry.chemical_classification Primary (chemistry)Hydride Chemistry Oppenauer oxidation General Medicine Bridged compounds Medicinal chemistry Acceptor

description

1,1,1-Trifluoroacetone (2a) reacts as a hydride-acceptor in the Oppenauer oxidation of secondary alcohols (1) in the presence of diethylethoxyaluminum. The oxidant allows for selective oxidation of secondary alcohols in the presence of primary alcohols.

year	journal	country	edition	language
2008-03-25	ChemInform

https://doi.org/10.1002/chin.200813031

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