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RESEARCH PRODUCT
Complexes of organometallic compounds
M. AiroldiGiuseppina FaragliaNuccio Bertazzisubject
StereochemistryCyanidePotassiumCoordination numberIodideInorganic chemistrychemistry.chemical_elementInfrared spectroscopyMedicinal chemistryElectron spectroscopyBiochemistryAnalytical ChemistryCoordination complexInorganic Chemistrychemistry.chemical_compoundMaterials ChemistryOrganic chemistryChelationPhysical and Theoretical ChemistryGroup 2 organometallic chemistrychemistry.chemical_classificationChromatographyIon exchangeLigandOrganic ChemistryGeneral MedicinePaper chromatographyCrystallographychemistryStoichiometrydescription
Abstract Several new complexes formed by PhTlCl 2 with tridentate ligands (with ONO and SNO donor atoms) and a tetradentate ligand (with ONNO donor atoms), have been prepared. The complexes show 1/1 organothallium(lll)/Ligand ( = L 2− ) stoichiometry. Their nature and configuration are investigated in the solid state by vibrational spectroscopy, and in solution by electronic spectroscopy. The existence of chelation by the dianionic ligands on Tl III is inferred, and suggestions are made concerning the Tl III coordination number and the stereochemistry of the complexes.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1974-12-01 | Journal of Organometallic Chemistry |