6533b7dafe1ef96bd126dfa2
RESEARCH PRODUCT
Proton coordination by polyamine compounds in aqueous solution
Antonio BianchiAndrea BenciniJose Antonio RamirezMauro MicheloniEnrique García-españasubject
Aqueous solutionProtonChemistryInorganic chemistryProtonationInorganic Chemistrychemistry.chemical_compoundComputational chemistryMaterials ChemistryPhysical and Theoretical ChemistryMolecular topologyNuclear ExperimentPolyamineElectronic propertiesdescription
Abstract The present article is concerned with proton transfer reactions in aqueous solution of open-chain, macrocyclic and macropolycyclic or cage compounds having nitrogen atoms as protonation sites in the molecular framework, although several compounds with additional different donors will be considered. The main purpose of this review is to collect some significant examples of proton transfer processes in order to show how the electronic properties and molecular topology of polyamines affect the thermodynamic parameters of their protonation equilibria.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1999-07-01 | Coordination Chemistry Reviews |