6533b7dafe1ef96bd126e05f

RESEARCH PRODUCT

ChemInform Abstract: Stereoselective Synthesis of β-1-O-Acyl Derivatives of Carbohydrates: An Application of the Cesium Effect.

Horst KunzRichard KullmannJörg ZimmerPeter Wernig

subject

chemistryCaesiumOrganic chemistrychemistry.chemical_elementlipids (amino acids peptides and proteins)StereoselectivityGeneral Medicine

description

Abstract The stereoselective formation of anomerically pure 1-O-acyl derivatives of protected carbohydrates is achieved by reaction of the α-glycosyl halogenoses with cesium caboxylates.

https://doi.org/10.1002/chin.199241240