6533b7dafe1ef96bd126ec54

RESEARCH PRODUCT

Frequency-modulation spectroscopy with blue diode lasers

Janis AlnisGabriel SomesfaleanSune SvanbergU Gustafsson

subject

Tunable diode laser absorption spectroscopyMaterials scienceAbsorption spectroscopyInfraredbusiness.industryMaterials Science (miscellaneous)Atom and Molecular Physics and OpticsInfrared spectroscopyLaserIndustrial and Manufacturing Engineeringlaw.inventionOpticslawOptoelectronicsBusiness and International ManagementTime-resolved spectroscopyLaser-induced fluorescencebusinessSpectroscopy

description

Frequency-modulation spectroscopy provides ultrasensitive absorption measurements. The technique is especially adaptable to diode lasers, which can be modulated easily, and has been used extensively in the near-infrared and infrared spectral regions. The availability of blue diode lasers now means that the accessible wavelength region can be increased. We successfully demonstrate wavelength-modulation spectroscopy and two-tone frequency-modulation spectroscopy for the weak second resonance line of potassium at 404.8 nm and for the transition at 405.8 nm in lead, starting from the thermally populated 6p(2) P-3(2) metastable level, information on the modulation parameters is obtained with a fitting procedure. Experimental signal-to-noise ratios: at different absorption levels are compared with theoretical signal-to-noise ratios and show good agreement. Detection sensitivities of 2 x 10(-6) and 5 x 10(-6) for wavelength and two-tone frequency-modulation spectroscopy, respectively, for a 120-Hz bandwidth are demonstrated. (C) 2000 Optical Society of America.

10.1364/ao.39.003774https://lup.lub.lu.se/record/2258305