6533b7dafe1ef96bd126f4f5

RESEARCH PRODUCT

Supramolecular stabilization of the phosphite-based polyoxomolybdate [Mo6(PO3)(HPO3)3O18]9−

Carlos Martí-gastaldoJosé R. Galán Mascarós

subject

Inorganic ChemistryCrystallographychemistryOctahedronHydrogen bondMolybdenumMaterials ChemistrySupramolecular chemistryCluster (physics)Solid-statechemistry.chemical_elementPhysical and Theoretical ChemistryPhotochemistry

description

Abstract A novel phosphite-based hetero-polyoxomolybdate, [Mo 6 (PO 3 )(HPO 3 ) 3 O 18 ] 9− , has been isolated and structurally characterized. The most striking feature of this polyanion is the presence of peripheral phosphite groups linked to the MoO 6 octahedra. In the solid state, this cluster shows strong hydrogen bonding interactions that apparently play a key role in its stabilization and isolation from solution.

yearjournalcountryeditionlanguage
2007-02-01Polyhedron
https://doi.org/10.1016/j.poly.2006.08.030