Palladium-Catalyzed Skeletal Rearrangement of Spirotricyclic Olefins: A Facile One-Pot Strategy for the Synthesis of a Novel Motif with Cyclopentene Fused to Benzofuran and Pyrazolidine

6533b7dafe1ef96bd126f5c6

RESEARCH PRODUCT

Palladium-Catalyzed Skeletal Rearrangement of Spirotricyclic Olefins: A Facile One-Pot Strategy for the Synthesis of a Novel Motif with Cyclopentene Fused to Benzofuran and Pyrazolidine

Sarngadharan Sarath Chand Kokkuvayil Vasu Radhakrishnan E. Jijy Petri M. Pihko Praveen Prakash Preethalayam Preethanuj

subject

Stereochemistry Organic Chemistry chemistry.chemical_element General Chemistry Catalysis Coupling reaction Catalysis Cyclopropane Pyrazolidine chemistry.chemical_compound Stereospecificity chemistry Cyclopentene Benzofuran ta116 Palladium

description

The first utilization of acyclic cyclopropane bearing spirocyclic olefines for the generation of stereospecific complex fused ring systems with an achiral catalyst is reported.

year	journal	country	edition	language
2013-06-20	Chemistry - A European Journal

https://doi.org/10.1002/chem.201301475

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